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Although the dollar value of the krona survived World War I almost unimpaired, it shared in the general devaluations of 1931, 1949, and later In the nineteenth and early twentieth centuries, Swedish interest rates were higher than those of many European countries reviewed In the 1930 s and 1940 s, Swedish interest rates declined with other rates In the 1950 s, Swedish rates rose somewhat less than did rates in most countries reviewed The net result was that Swedish rates by 1960 were about average and were no longer above those of most other countries After 1960, Swedish rates followed the pattern of most Western countries, with a few exceptions noted below.

PROBLEMS 2-1 Derive an expression for the rate of polymerization of stoichiometric amounts of adipic acid and hexamethylene diamine. Indicate the assumptions inherent in the derivation. Derive an expression for the rate of polymerization of nonstoichiometric amounts of the two reactants. A 21.3-g sample of poly(hexamethylene adipamide) is found to contain 2:50 10 3 mol of carboxyl groups by both titration with base and infrared spectroscopy. From these data the polymer is calculated to have a number-average molecular weight of 8520. What assumption is made in the calculation How can one experimentally obtain the correct value of M n Describe and draw the structure of the polyester obtained in each of the following polymerizations:

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Will the structure of the polymer produced in each case depend on the relative amounts of the reactants If so, describe the differences. 2-4 Describe and draw the structure of the polyester obtained in each of the following polymerizations:

Will the structure of the polymer produced in each of cases b, c, and d depend on the relative amounts of the reactants If so, describe the differences. 2-5 Compare the molecular weight distributions that are expected for the polymerizations in Problems 2-3a, 2-4a, 2-4b, and 2-4c.

Swedish interest rates are presented in Table 72 in three series: (a) the official discount rate charged by the Bank of Sweden in terms of an annual average and annual range; (b) the effective rates on new issues of long-term government bonds until 1945; and (c) the market yields of long-term government bonds from 1922 based on an annual average of the yield Chart 74 pictures decennial averages of the official discount rate from 1830 and of long-term government bond yields from 1856 The same series are represented as annual averages from 1900 in Chart 75 The annual averages of Swedish bond yields in general followed the American, English, and Dutch pattern throughout this century They rose until 1920, fell until 1938 1948, and then rose again The tendency toward relatively lower rates was by no means as pronounced as in Switzerland, but it was noticeable.

Discuss the possibility of cyclization in the polymerization of a. H2N (CH2)m CO2H b. HO (CH2)2 OH + HO2C

Dremel drill sets have come a long way in the past twenty years (see Figure 5-8).

for the cases where m has values from 2 to 10 At what stage(s) in the reaction is cyclization possible What factors determine whether cyclization or linear polymerization is the predominant reaction 2-7 Show that the time required to go from p 0:98 to p 0:99 is very close to the time to reach p 0:98 from the start of polymerization for the external acid-catalyzed polymerization of an equimolar mixture of a diol and diacid The polymerization between equimolar amounts of a diol and diacid proceeds with an equilibrium constant of 200.

It was a characteristic shared by these two prominent neutral countries Swedish government bond yields were above American corporate bond yields and far above most European government bond yields when the twentieth century began They had come down to below 4% during the last few years of the nineteenth century, but there was no period of very low yields at the turn of the century such as was common elsewhere..

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