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The decennial averages of Swiss short rates remained far below the low decennial average of Swiss bond yields and below short-term averages in other countries, but the long-short differential tended to narrow in the 1970 s and 1980 s, and it even reversed in the early 1990 s (see 29) AUSTRIA Austrian interest rates are represented in Table 98 by the official discount rate from 1935 and the government bond yield from 1965 The history of interest rates in the Austro-Hungarian Empire in the nineteenth and early twentieth centuries is omitted because it closely paralleled German interest-rate history, was comparatively brief, and came to an end in 1918 In the 1930 s the official Austrian discount rate was pegged at 350% After the end of World War II, this rate was resumed In 1951, there was.

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Fig. 3-13 Dependence of the polymerization rate (*) and polymer molecular weight (&) on the temperature for the thermal self-initiated polymerization of styrene. After Roche and Price [1952] (by permission of Dow Chemical Co., Midland, MI).

A socket driver looks like a screwdriver except that where the tip of the blade would be is a socket similar to the sockets in a ratchet wrench socket set. You ll also want a set of socket drivers, again in standard and metric, sized from 3 4" on down to 1 4". Be sure to get socket drivers for electronics, because these have hollow shafts instead of solid. The hollow shaft allows the handle of toggle switches and other components a recess while the wrench tightens their hardware (see Figure 5-7).

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Note that the variations in the values of Ap , the frequency factor for propagation, are much greater than those in Ep indicating that steric effects are probably the more important factor in determining the absolute value of kp . Thus the more hindered monomers, such as methyl methacrylate and dimethyl itaconate (dimethyl 2-methylenebutanedioic acid), have lower kp and Ap values than the less hindered monomers. The Ap values in general are much lower than the usual value (1011 1013 ) of the frequency factor for a bimolecular reaction probably due to a large decrease in entropy on polymerization. The variations in At , the frequency factor for termination, generally follow along the same lines as the Ap values. The At values in general are larger than the Ap values. 3-9a-1 Rate of Polymerization

Consider the activation energy for various radical chain polymerizations. For a polymerization initiated by the thermal decomposition of an initiator, the polymerization rate depends on the ratio of three rate constants kp (kd =kt 1=2 in accordance with Eq. 3-32. The temperature dependence of this ratio, obtained by combining three separate Arrhenius-type equations, is given by

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a return to a flexible monetary policy; the discount rate rose to the comparatively high level of 550% in 1952, but the average for the 1950 s was only 452%, which was also the average for the 1960 s In the 1970 s, the average rose to 513% The Austrian discount rate reached a twentiethcentury peak of 675% in 1980 1981, but the average for the 1980 s fell back to 470% Austrian government bond yields after 1965 followed the rising pattern seen elsewhere, but only once in 1981 averaged above 10% in any year Austria had become a country of stability and relatively low rates SWEDEN Sweden, like Switzerland, was permitted by her belligerent neighbors to remain neutral and at peace during both of the great wars of the twentieth century Sweden, however, did not enjoy Switzerland s economic stability.

" # " # kd 1=2 Ad 1=2 Ep Ed =2 Et =2 ln kp ln Ap RT kt At 3-168

Zavitsas, A. A., J. Polym. Sci., A-1(6), 2533 (1968). Zavitsas, A. A., R. D. Beaulieu, and J. R. LeBlanc, J. Polym. Sci., A-1(6), 2541 (1968). Zimmerman, J., Polyamides, pp. 315 381, in Encyclopedia of Polymer Science and Engineering, Vol. 11, H. F. Mark, N. M. Bikales, C. G. Overberger, and G. Menges, eds., Wiley-Interscience, New York, 1988. Zimmerman, J. and M. I. Kohan, J. Polym. Sci. Polym. Chem. Ed., 39, 2565 (2001). Zvetkov, V. L., Macromol. Chem. Phys., 203, 467 (2002).

What about power drivers A good-quality, power-drill-type screwdriver is a great addition to the bender s bench. My RYOBI 7.2-volt power driver has an adjustable clutch (to keep from overdriving), has good balance, holds a charge well, and is one of a few mid-to-low-priced power drivers available (be sure to buy a set of long bits 2" to 3" if your power driver is not supplied with such). However, the emphasis in this book will be on hand tools, because most tool applications here are hand tool only, and because practice with hand tools of all types will hone bending skills and better familiarize the bender with the materials at hand.

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